CHM 241-601

Organic Chemistry I

William A. Price, Ph.D.

 

Chapter 6-Alkyl Halides

problems from L.G. Wade, 6th edition

 

Topic

In-chapter problems

End-of-chapter problems

Vocabulary

 

41

Classification & naming

1-3

42,43

Free radical halogenation

8-10

63,64

Subst. And Elim. (overview)

11,12

 

Kinetics

 

48,49,67

SN2 (general)

13-15,17,32,35

46,47,56

Nucleophiles, substrates, leaving groups

16,18,19

44,50

Stereochemistry of SN2

20,21

55,57,59

SN1

36

51

Nucleophiles, substrates, leaving groups

22-24

45

Mechanism, carbocation rearrangements

25,26,29

53,54,65

Allylic and benzylic cations

 

52

SN1 & SN2

27

62b)

E1

30,31

60,61,62a)

E1 & SN1

 

66,73

E2

37

 

Saytzeff rule

34

 

E1 & E2

33,37

 

Stereochemistry of E2

38

68,71,72

Combined

40

74*, 75*